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Baird's rule : ウィキペディア英語版 | Baird's rule In organic chemistry, Baird's rule estimates whether a lowest triplet state of planar ring molecule will have aromatic properties. The quantum mechanical basis for its formulation was first worked out by physical chemist N. Colin Baird in 1972. A lowest triplet state of cyclic ring molecule follows Baird's rule when the number of its π-electrons equals 4''n'' where ''n'' is any positive integer. However, in most cases the lowest triplet state of cyclic ring has higher energy then the lowest singlet state of cyclic ring due to Jahn–Teller effect. ==See also==
* Möbius–Hückel concept * Möbius aromaticity * Hückel's rule
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